In this project the boundaries of what can be achieved in SMOM (solid-state molecular organometallic) chemistry will be pushed back, in both synthesis and catalysis. In particular we are interested in how the molecular structure of the organometallic complexes in crystallo can be fine-tuned to develop selective catalysts for a variety of different transformations of simple feedstocks (alkanes, alkenes, and other small molecules), that also operate at close to room temperature with high conversions. The project will develop new synthetic routes to in crystallo organometallics, study their fundamental reactivity, deployment in catalysis (batch or flow) and the interrogation of kinetics and mechanism.
The post is ideally suited to someone who is willing to take on a synthetic challenge, problem-solve in a collaborative team environment, and further develop their skills by using a wide variety of techniques to resolve structure, bonding and reactivity in organometallic systems.
United Kingdom Academic Chemistry On-site PhD Required Physics Solid State Physics University of York